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Structural and Electronic Paradigms in Cluster Chemistry

Roy L. Johnston (auth.), Prof. D. M. P. Mingos (eds.)

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مشخصات کتاب

نویسنده
Roy L. Johnston (auth.), Prof. D. M. P. Mingos (eds.)
ناشر
Springer-Verlag Berlin Heidelberg
سال انتشار
۱۹۹۷
فرمت
PDF
زبان
انگلیسی
تعداد صفحات
۲۰ صفحه
حجم فایل
۳٫۲ مگابایت

دربارهٔ کتاب

It is 25 years since the seminal papers describing the relationships between the skeletal geometrics and closed shell electronic requirements of metal clusters were originally published. The electron counting rules which developed from these papers, are now to be found in all undergraduate inorganic textbooks. This volume provides a contemporary account of recent applications of the methodology and the mathematical foundations of the rules. In addition it describes how it is possible to accomondate acception to the rules within a wider framework. The authors are the foremost authorities in the field and give a broad introduction to the area. Mathematical cluster chemistry....Pages 1-34 Metal-metal interactions in transition metal clusters with π -donor ligands....Pages 35-80 Electron count versus structural arrangement in clusters based on a cubic transition metal core with bridging main group elements....Pages 81-109 Metallaboranes....Pages 111-135 Clusters with interstitial atoms from the p -block: How do Wade's rules handle them?....Pages 137-156 Diverse naked clusters of the heavy main-group elements. Electronic regularities and analogies....Pages 157-193

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