Chemical and Biochemical Technology : Materials, Processing, and Reliability

By providing an applied and modern approach, this volume will help readers understand the value and relevance of studying chemical physics and technology to all areas of applied chemical engineering, and gives them the depth of coverage they need to develop a solid understanding of the key principles in the field. Presenting a wide-ranging view of current developments in applied methodologies in chemical and biochemical physics research, the papers in this collection, all written by highly regarded experts in the field, examine various aspects of chemical and biochemical physics and experimentation. The book: • Highlights applications of chemical physics to subjects that chemical engineering students will see in graduate courses • Introduces the types of challenges and real problems that are encountered in industry and graduate research • Provides short chapters that introduce students to the subject in more bite-sized pieces • Presents biochemical examples and applications • Focuses on concepts above formal experimental techniques and theoretical methods The book is ideal for upper-level research students in chemistry, chemical engineering, and polymers. The book assumes a working knowledge of calculus, physics, and chemistry, but no prior knowledge of polymers. 1. Electrophysical properties of carbon nanostructures with defects in a strong external electric field / S.A. Sudorgin and N.G. Lebedev 2. Topology and geometry of protein water shell by computer modeling / E.V. Rubtcova, A.B. Solovey, and V.I. Lobyshev 3. Optimization of molecular models for calculating quantum yields of photochemical reactions / V.I. Baranov, I.V. Mikhailov, and N.I. Poteshnay 4. Furacilinum release from polyhydroxybutyrate-schungite films / A.A. Olkhov, A.L. Iordanskii, and G.E. Zaikov 5. Structure of UV-protective nanocomposites films based on polyethylene / A.A. Olkhov, M.A. Goldshtrakh, G. Nyszko, K. Majewski, J. Pielichowski, and G.E. Zaikov 6. Identification of the acidic air pollution by IR spectroscopic study of epiphytic lichens / A.F. Meysurova, S.D. Khizhnyak, and P.M. Pakhomov 7. The reactivity of fluoro- and chloro-substituents of ethylene with ozone : quantum-chemical calculation / E.A. Mamin Eldar Alievich, B.E. Krisyuk, A.V. Maiorov, and A.A. Popov 8. Usage of speed sedimentation method for enzyme degradation of chitosan / V.V. Chernova, E.I. Kulish, I.F. Tuktarova, and G.E. Zaikov 9. Double-decker phthalocyanines : spectral redox properties and sensor elements based on them / G.A. Gromova and A.V. Lobanov 10. Microwave synthesis and electronic structure studies of lantanide tetraarylporphyrin complexes / A.S. Gorshkova, S.V. Gorbachev, E.V. Kopylova, V.D. Rumyantseva, R.N. Mozhchil, and A.M. Ionov 11. Same concepts of cosmology in the modern natural science / M.D. Goldfein and A.V. Ivanov 12. A commentary on the concepts of the physical chemistry of polymers in technologies and environment protection / M.D. Goldfein and N.V. Kozhevnikov 13. Aggregation behavior of unsubstituted metal phthalocyanines in supramolecular systems / G.S. Dmitrieva and A.V. Lobanov 14. Thermoplastic composites of polypropylene and ethylene-octene rubber / Maria Rajkiewicz, Marcin Śla̧czka, and Jakub Czakaj. 15. A lecture note on cultivation of legume grasses for seeds in mountain zone / S.A. Bekuzarova, I.M. Khaniyeva, and L.S. Ghishkayeva 16. Red clover (trifolium pratense L.) for hayfield-pasture use / S.A. Bekuzarova and V.A. Belyayeva 17. A lecture note on restoration of biodiversity in mountain plant communities by means of selection / S.A. Bekuzarova 18. Biology of development of phytopathogenic fungi of fusariumlink and resistance of cereals to it in climatic conditions of Tyumen Region / N.A. Bome, A. Ja. Bome, and N.N. Kolokolova 19. The basic characteristics of continuously cultivated sod-podzol soil of Northern Territories (in the case of Tobolsk District, Tyumen Region) / I.A. Dudareva (Cherkashina) and N.A. Bome 20. A lecture note on the efficiency of the use of crop produce for alternative fuel production / A.V. Doronin 21. Orientation controlled immobilization strategy for SS-Galactosidase on alginate beads / M.S. Mohy Eldin, M.R. El-Aassar, and E.A. Hassan 22. Regenerationpotential of pear cultivars and species (Pyrus L.) of the collection of the national dendrological park "sofiyivka" of Nas of Ukraine / Anatoliy Iv. Opalko, Nataliya M. Kucher, and Olga A. Opalko 23. The prostor and ferm KM complex probiotic additives : biotechnological preparations for enhancing the quality of domestic fish mixed feed / D.S. Pavlov, N.A. Ushakova, V.G. Pravdin, L.Z. Kravtsova, C.A. Liman, and S.V. Ponomarev 24. Variability of combining abilities of MS (male sterility) lines and sterility binders of sugar beets as to sugar content / Korneeva Myroslava Oleksandrivna and Nenka Maksym Mykolayovych 25. Comparison of chromosomal rearrangements in early seedlings of Crepis capillaris L. after treatment of seeds by X-Rays and by the chemical mutagen / L.I. Weisfeld. Front Cover 1 CONTENTS 10 List of Contributors 14 List of Abbreviations 20 List of Symbols 22 Preface 24 1. Electrophysical Properties of Carbon Nanostructures with Defects in a Strong External Electric Field 26 2. Topology and Geometry of Protein Water Shell by Computer Modeling 38 3. Optimization of Molecular Models for Calculating Quantum Yields of Photochemical Reactions 60 4. Furacilinum Release from Polyhydroxybutyrate-Schungite Films 80 5. Structure of UV-Protective Nanocomposites Films Based on Polyethylene 90 6. Identification of the Acidic Air Pollution by IR Spectroscopic Study of Epiphytic Lichens 104 7. The Reactivity of Fluoro- and Chloro-substituents of Ethylene with Ozone: Quantum-Chemical Calculation 118 8. Usage of Speed Sedimentation Method for Enzyme Degradation of Chitosan 132 9. Double-Decker Phthalocyanines: Spectral Redox Properties and Sensor Elements Based on Them 140 10. Microwave Synthesis and Electronic Structure Studies of Lantanide Tetraarylporphyrin Complexes 154 11. Same Concepts of Cosmology in the Modern Natural Science 178 12. A Commentary on the Concepts of the Physical Chemistry of Polymers in Technologies and Environment Protection 200 13. Aggregation Behavior of Unsubstituted Metal Phthalocyanines in Supramolecular Systems 212 14. Thermoplastic Composites of Polypropylene and Ethylene-Octene Rubber 226 15. A Lecture Note on Cultivation of Legume Grasses for Seeds in Mountain Zone 240 16. Red Clover (Trifolium pratense L.) for Hayfield-Pasture Use 246 17. A Lecture Note on Restoration of Biodiversity in Mountain Plant Communities by Means of Selection 260 18. Biology of Development of Phytopathogenic Fungi of Fusariumlinkand Resistance of Cereals to It in Climatic Conditions of Tyumen Region 270 19. The Basic Characteristics of Continuously Cultivated Sod-Podzol Soilof Northern Territories (in the Case of Tobolsk District,Tyumen Region) 278 20. A Lecture Note on the Efficiency of the Use of Crop Produce for Alternative Fuel Production 288 21. Orientation Controlled Immobilization Strategy for β-Galactosidase on Alginate Beads 304 22. Regenerationpotential of Pear Cultivars and Species (Pyrus L.) of the Collection of the National Dendrological Park “Sofiyivka” of Nas of Ukraine 324 23. The Prostor and Ferm KM Complex Probiotic Additives: Biotechnological Preparations for Enhancing the Quality of Domestic Fish Mixed Feed 338 24. Variability of Combining Abilities of MS (Male Sterility) Lines and Sterility Binders of Sugar Beets as to Sugar Content 346 25. Comparison of Chromosomal Rearrangements in Early Seedlings of Crepis capillaris L. After Treatment of Seeds by X-Rays and by the Chemical Mutagen 358 PrefaceElectrophysical Properties of Carbon Nanostructures With Defects in a Strong External Electric Field; S. A. Sudorgin and N. G. LebedevTopology and Geometry of Protein Water Shell by Computer Modeling; E. V. Rubtcova, A. B. Solovey, and V. I. LobyshevOptimization of Molecular Models For Calculating Quantum Yields of Photochemical Reactions; V. I. Baranov, I. V. Mikhailov, and N. I. PoteshnayFuracilinum Release from Polyhydroxybutyrate-Schungite Films; A. A. Olkhov, A. L. Iordanskii, and G. E. ZaikovStructure of UV-Protective Nanocomposites Films Based on Polyethylene; A. A. Olkhov, M. A. Goldshtrakh, G. Nyszko, K. Majewski, J. Pielichowski, and G. E. ZaikovIdentification of the Acidic Air Pollution by Ir Spectroscopic Study of Epiphytic Lichens; A. F. Meysurova, S. D. Khizhnyak, and P. M. PakhomovThe Reactivity of Fluor- and Chlorsubstituents of Ethylene With Ozone: Quantum-Chemical Calculation; E. A. Mamin Eldar Alievich, B. E. Krisyuk, A. V. Maiorov, Aand . A. PopovUsage of Speed Sedimentation Method for Enzyme Degradation of Chitosan; V. V. Chernova, E. I. Kulish, I. F. Tuktarova, and G. E. ZaikovDouble-Decker Phthalocyanines: Spectral Redox Properties and Sensor Elements Based on Them; G. A. Gromova and A. V. LobanovMicrowave Synthesis and Electronic Structure Studies of Lantanide Tetraarylporphyrin Complexes; A. S. Gorshkova, S. V. Gorbachev, E. V. Kopylova, V. D. Rumyantseva, R. N. Mozhchil, and A. M. IonovSame Concepts of Cosmology in the Modern Natural Science; M. D. Goldfein and A. V. IvanovA Commentary on the Concepts of the Physical Chemistry of Polymers in Technologies and Environment Protection; M. D. Goldfein and N. V. KozhevnikovAggregation Behavior of Unsubstituted Metal Phthalocyanines in Supramolecular Systems; G. S. Dmitrieva and A. V. LobanovThermoplastic Composites of Polypropylene and Ethylene-Octene Rubber; Maria..