Ionic Liquids - Classes and Properties

preface_ Ionic Liquids – Classes and Properties......Page 1 Part_ 1......Page 17 01_1,2,3-Triazolium Salts as a Versatile New Class of Ionic Liquids......Page 19 02_Thiazolium and Benzothiazolium Ionic Liquids......Page 39 03_Glycoside-Based Ionic Liquids......Page 81 04_Ionic Liquids from (Meth) Acrylic Compounds......Page 97 Part _2......Page 121 05_Theoretical Description of Ionic Liquids......Page 123 06_Classical Density Functional Theory of Ionic Liquids......Page 143 Part_3......Page 167 07_Interactions and Transitions in Imidazolium Cation Based Ionic Liquids......Page 169 08_High Pressure Phase Behavior of Two Imidazolium-Based Ionic Liquids, [bmim][BF4] and [bmim][PF6]......Page 187 09_Dielectric Properties of Ionic Liquids Proposed to Be Used in Batteries......Page 203 10_Translational and Rotational Motions for TFSA-Based Ionic Liquids Studied by NMR Spectroscopy......Page 225 Part 4......Page 253 11_Ionic Liquids Recycling for Reuse......Page 255 12_Ionic Liquids in Green Carbonate Synthesis......Page 289 13_Ionic Liquids in Polar Diels-Alder Reactions Using Carbocycles and Heterocycles as Dienophiles......Page 327 Room temperature ionic liquids (RTILs) are an interesting and valuable family of compounds. Although they are all salts, their components can vary considerably, including imidazolium, pyridinium, ammonium, phosphonium, thiazolium, and triazolium cations. In general, these cations have been combined with weakly coordinating anions. Common examples include tetrafluoroborate, hexafluorophosphate, triflate, triflimide, and dicyanimide. The list of possible anionic components continues to grow at a rapid rate. Besides exploring new anionic and cation components, another active and important area of research is the determinination and prediction of their physical properties, particularly since their unusual and tunable properties are so often mentioned as being one of the key advantages of RTILs over conventional solvents. Despite impressive progress, much work remains before the true power of RTILs as designer solvents (i.e. predictable selection of a particular RTIL for any given application) can be effectively harnessed